French Open champion Anastasia Myskina crashed out of the German Open 6-2 1-6 6-4 to German wildcard Julia Schruff.
The Russian third seed, who had a bye into the second round, fought back well after a poor start.
But she was undone by unforced errors in the decider and 22-year-old Schruff, ranked 107, clinched a popular win.
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